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Following very shortly after this discovery was the realization that lamellar crystals of polymers other than polyethylene also exhibited chain folding Many distinctive properties of these polymers follow as a consequence of this phenomenon, often known as chain folding because molecules generally fold back and forth across the thin. In 1957, keller deduced that long polyethylene (pe) chains fold to form thin single lamellar crystals, with the molecular chains perpendicular to the flat faces of the crystals (the.
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As we have seen, long chain polymers only crystallize at finite rates at high undercoolings, so only form folded chain structures. The orientation of the electron diffraction patterns from individual lamellar crystals establishes that the polymer chains lie perpendicular to the lamellar surface and that the folding plane is parallel to the long axis of the crystal.
